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Lecturer(s)
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Vestfálová Magda, Ing. Ph.D.
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Course content
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Introduction, basic postulates and laws of thermodynamics. Simple ( = one components homogeneous) systems: thermal equation of state - energy functions - heat capacity - the general shapes of the thermodynamic equation of state - deviations of variables from the idealized states - the absolute value of entropy - open thermodynamic systems - the chemical potential. Multicomponent systems without chemical reactions: state of system - Gibbs phase rule - molar, volumetric and thermal balance of mixing processes - integral, partial molar and partial molar mixing quantities - two component two phase ideal systems. One component heterogeneous systems: phase diagrams showing phase changes - thermodynamic properties of two phases - equilibrium conditions - Clausius-Clapeyron equation Thermochemistry: stoichiometric equations - mass balance - volumetric balance - first law of thermodynamics applied to chemical equations - the reaction enthalpy and energy - II . law of thermodynamics applied to chemical equations - chemical equilibrium - range of reactions - equilibrium constant - the basics of combustion
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Learning activities and teaching methods
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Monological explanation (lecture, presentation,briefing), Self-study (text study, reading, problematic tasks, practical tasks, experiments, research, written assignments)
- Class attendance
- 56 hours per semester
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Learning outcomes
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Thermodynamic properties of real substances. Energy and entropy forms of the Gibbs fundamental equations and the use of properties of energetic functions to describe thermodynamic properties. Thermodynamic properties during the phases changes. Thermodynamic properties of the ideal and real mixtures. Application of solution procedures to technical problems.
Deeper knowledges in thermodynamics
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Prerequisites
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Exam in Thermodynamics and heat transport
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Assessment methods and criteria
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Combined examination
Credit: max. Allowed 25% excused absence with replacement processing of missing topics. Exam: written - demonstration of knowledge of the discussed areas, the condition of participation in the exam is to obtain a credit.
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Recommended literature
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Bird R. B., Stewart W. E., Lightfoot E. N.:. Přenosové jevy. Praha, 1968.
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Cengel Y. A. Thermodynamics, An Engineering Approach. 2015.
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Hála E.:. Úvod do chemické termodynamiky. Praha, 1975.
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Kolářová H., Šedivý V., Šulc R.:. Základy fyzikální chemie. Praha, 2011. ISBN 978-80-01-03903-8.
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Maca K.:. Základy fyzikální chemie. Brno, 2005.
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Moran M.J., Shapiro H.N.:. Fundamentals of Engineering Thermodynamics. New York, 1992.
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Středa I.:. Termodynamika. Praha, 1993.
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